涤纶表面TiO<sub>2</sub>薄膜的制备及抗紫外线性能研究

成娅; 陈卓明; 郑元生; 辛斌杰

涤纶表面TiO₂薄膜的制备及抗紫外线性能研究

上海工程技术大学纺织服装学院, 上海201620

详细信息

作者简介:
成娅：成　娅（1998−），女，在读硕士，研究方向为纤维表面功能化处理、柔性可穿戴纺织品. Email：091317107@sues.edu.cn

通讯作者:
陈卓明（1986−），女，讲师，博士，研究方向为纤维表面功能化处理、柔性可穿戴纺织品. Email：chenzm@sues.edu.cn

中图分类号: TS101.3；TS103.6
计量
- 文章访问数: 459
- HTML全文浏览量: 1299
- PDF下载量: 865
- 被引次数: 0
出版历程
- 收稿日期: 2021-12-10
- 录用日期: 2021-12-10
- 刊出日期: 2022-02-23

Study on preparation and anti-UV properties of TiO₂ film on terylene

School of Textiles and Fashion, Shanghai University of Engineering Science, Shanghai 201620, China

摘要

摘要: 通过磁控溅射将二氧化钛（TiO₂）沉积在涤纶织物表面形成薄膜，制备二氧化钛/涤纶（TiO₂/PET）抗紫外线功能织物，探讨制备过程中磁控溅射时间和溅射功率对织物抗紫外线功能的影响，分析TiO₂薄膜的紫外线吸收和屏蔽机理，同时检测织物隔热、热稳定性能的变化情况. 结果表明：在PET织物表面沉积TiO₂薄膜可改善织物的抗紫外线性能，归因于TiO₂薄膜对紫外光较好的吸收和对紫外可见光有效的屏蔽能力；且因TiO₂薄膜在溅射150 W以上的功率下粗糙度增加、厚度减少，当溅射功率为150 W，溅射时间为90 min时，TiO₂/PET织物具有较强的抗紫外线能力，其紫外线防护系数（Ultraviolet Protection Factor，UPF）达到1211.19；同时，TiO₂薄膜的沉积赋予了PET织物良好的热稳定性能和隔热性能.
- 磁控溅射 /
- 涤纶 /
- 二氧化钛薄膜 /
- 抗紫外线性能
Abstract: Titanium dioxide/polyester (TiO₂/PET) ultraviolet (UV) resistant fabric was prepared by deposition of titanium dioxide on the surface of polyester fabric by magnetron sputtering. The effects of magnetron sputtering time and sputtering power on the UV resistance of the fabric during the preparation process were investigated. The UV absorption and shielding mechanism of TiO₂ thin films were analyzed, and the thermal insulation and thermal stability of the fabric were also detected. The results show that TiO₂ film deposited on the surface of PET can improve the UV resistance of the fabric, which is attributed to the good UV absorption capacity of TiO₂ film and the effective shielding ability of UV visible light. In addition, the roughness of TiO₂ film increases and the thickness decreases when the sputtering power is greater than 150 W, so when the sputtering power is 150 W and the sputtering time is 90 min, TiO₂/PET fabric has the strongest UV resistance, and its UV protection coefficient (UPF) is 1211.19. Simultaneously, the deposition of TiO₂ thin film endows the PET fabric with good thermal stability and heat insulation performance.
- magnetic sputtering /
- PET fabric /
- TiO₂ film /
- UV-resistant properties

HTML全文

图 1 磁控溅射沉积TiO₂工艺流程图

Figure 1. Flow chart of TiO₂ deposition by magnetron sputtering

下载: 全尺寸图片幻灯片

图 2 隔热性能测试原理图

Figure 2. Testing schematic of heat insulation performance

下载: 全尺寸图片幻灯片

图 3 涤纶织物溅射前后的照片以及织物样品在不同放大倍数下的显微镜图片

Figure 3. Photos of polyester fabric before and after sputtering and microscopic pictures of fabric samples at different magnifications

下载: 全尺寸图片幻灯片

图 4 TiO₂/PET织物在不同溅射条件下的抗紫外线性能

Figure 4. UV resistance of TiO₂/PET fabrics under different sputtering parameters

下载: 全尺寸图片幻灯片

图 5 TiO₂紫外可见光漫反射图谱^[3]

Figure 5. Ultraviolet and visible reflectance spectrum of TiO₂^[3]

下载: 全尺寸图片幻灯片

图 6 TiO₂/PET织物在不同溅射条件下的TG曲线

Figure 6. TG curves of TiO₂/PET fabric under different sputtering parameters

下载: 全尺寸图片幻灯片

图 7 TiO₂/PET织物在不同溅射条件下的DTG曲线

Figure 7. DTG curves of TiO₂/PET fabric under different sputtering parameters

下载: 全尺寸图片幻灯片

图 8 TiO₂/PET织物在不同溅射条件下的隔热性能

Figure 8. Thermal insulation performance of TiO₂/PET fabric under different sputtering parameters

下载: 全尺寸图片幻灯片

表 1 TiO₂ 薄膜的制备工艺参数

Table 1. Fabrication process parameters of TiO₂ films

组别溅射时间/min 溅射功率/W

A组 30 / 60 / 90 / 126 / 150 150
B组 90 50 / 100 / 150 / 260 / 250

下载: 导出CSV

参考文献(19)

[1]	刘珉, 胡鞍钢. 中国打造世界最大林业碳汇市场(2020-2050年)[J/OL]. 新疆师范大学学报(哲学社会科学版): 1-15 1-11-17].https://doi.org/10.14100/j.cnki.65-1039/g4.20211110.001.
[2]	付翠轻, 曹艳梅, 齐堃, 等. 试论消耗臭氧层物质的控制策略[J] . 产业创新,2020(8):5 − 106.
[3]	赵强, 刘正江, 马惠言, 等. TiO₂在织物功能整理中的应用机制和研究进展[J] . 毛纺科技,2021,49(9):102 − 107.
[4]	刘姝瑞, 张明宇, 谭艳君, 等. 纺织材料抗紫外改性的研究进展[J] . 纺织科学与工程学报,2021,38(2):54 − 59,85. doi: 10.3969/j.issn.2096-5184.2021.02.011
[5]	曹桂红, 彭新元. 织物防紫外线性能研究[J] . 湖南工程学院学报(自然科学版),2018,28(1):80 − 84.
[6]	刘姝瑞, 谭艳君, 霍倩, 等. 紫外UVB辐照PBO纤维老化机理及性能研究[J] . 染整技术,2017,39(1):14 − 19. doi: 10.3969/j.issn.1005-9350.2017.01.004
[7]	姚超, 张智宏, 林西平, 等. 纳米技术与纳米材料(V): 防晒化妆品中的纳米二氧化钛[J] . 日用化学工业,2003(5):333 − 336. doi: 10.3969/j.issn.1001-1803.2003.05.018
[8]	HU J T, GAO Q H, XU L, et al. Significant improvement in thermal and UV resistances of UHMWPE fabric through in situ formation of polysiloxane-TiO₂ hybrid layers[J] . Acs Applied Materials & Interfaces,2016(35):23311 − 23320.
[9]	杨豆豆, 孟家光, 白亚琴, 等. 纯棉针织物的纳米抗紫外整理[J] . 纺织高校基础科学学报,2020,33(2):11 − 16.
[10]	屠慕欣, 马越, 孙悦, 等. 漫谈防紫外线纺织品[J] . 辽宁丝绸,2020(2):58 − 59. doi: 10.3969/j.issn.1671-3389.2020.02.026
[11]	MEILLE V. Review on methods to deposit catalysts on structured surfaces[J] . Applied Catalysis A:General,2006,315:1 − 17. doi: 10.1016/j.apcata.2006.08.031
[12]	BOUKROUH S, BENSAHA R, BOURGEOIS S, et al. Reactive direct current magnetron sputtered TiO₂ thin films with amorphous to crystalline structures[J] . Thin Solid Films,2008,516(18):6353 − 6358. doi: 10.1016/j.tsf.2007.12.150
[13]	XU Y, XU W Z, HUANG F L, et al. Preparation and photocatalytic activity of TiO₂-deposited fabrics[J]. Inter-national Journal of Photoenergy, 2012, (1): 1 − 5. DOI: 10.1155/2012/852675.
[14]	王朝勇, 李伟, 王凯宏, 等. 直流磁控溅射制备锐钛矿TiO₂薄膜生长速率的研究及其在多层膜制备中的应用[J] . 真空,2020,57(5):19 − 23.
[15]	李刚. 磁控溅射法制备纳米TiO2薄膜及其光催化性能研究[D]. 郑州: 郑州大学, 2018.
[16]	HO C, LEE S B, BOO J H. Deposition of TiO₂ thin films using RF magnetron sputtering method and study of their surface characteristics[J] . Thin Solid Films,2005,475:183 − 188. doi: 10.1016/j.tsf.2004.08.033
[17]	TAN X Q, LIU J Y, NIU J R, et al. Recent progress in magnetron sputtering technology Used on fabrics[J] . Materials (Basel),2018,11(10):1953. doi: 10.3390/ma11101953
[18]	XU Y, WANG H F, WEI Q F, et al. Structures and properties of the polyester nonwovens coated with titanium dioxide by reactive sputtering[J] . Journal of Coatings Technology and Research,2010,7(5):637 − 642. doi: 10.1007/s11998-010-9243-8
[19]	XIAO X F, LIU F X, DONG F, et al. Highly Anti-UV properties of silk fiber with uniform and conformal nanoscale TiO₂ coatings via atomic layer deposition[J] . ACS Applied Materials & Interfaces,2015(38):21326 − 21333.