玻璃和微晶玻璃在固体氧化物燃料电池中的研究进展

王坤; 苏钰

玻璃和微晶玻璃在固体氧化物燃料电池中的研究进展

王坤,
苏钰^,

上海工程技术大学材料工程学院, 上海 201620

基金项目: 上海工程技术大学研究生科研创新资助项目（20KY0503）；上海工程技术大学课程建设资助项目（01040610）

详细信息

作者简介:
王坤：王　坤（1995−），男，在读硕士，研究方向为固体氧化物燃料电池. E-mail: 1901962908@qq.com

通讯作者:
苏　钰（1977−），女，副教授，博士，研究方向为高强钢成形性. E-mail: suyu@sues.edu.cn

中图分类号: TM911.4
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- 文章访问数: 523
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- 被引次数: 0
出版历程
- 收稿日期: 2021-06-03
- 刊出日期: 2021-09-30

Application of glass and glass-ceramics in solid oxide fuel cell

WANG Kun,
SU Yu^,

School of Materials Engineering, Shanghai University of Engineering Science, Shanghai 201620, China

摘要

摘要: 描述玻璃和微晶玻璃作为固体氧化物燃料电池(Solid Oxide Fuel Cell，SOFC)密封材料的使用要求. 尝试基于SOFC所用的玻璃和微晶玻璃进行分类，介绍基于不同体系的SOFC用密封玻璃(硅酸盐密封、硼硅酸密封、铝硅酸盐密封和硼铝硅酸盐密封)，并对玻璃和微晶玻璃在SOFC中的发展趋势进行展望.
- 固体氧化物燃料电池 /
- 玻璃 /
- 微晶玻璃 /
- 密封 /
- 热化学稳定性
Abstract: The application requirements of glass and glass-ceramics as solid oxide fuel cell (SOFC) sealing materials were described. An attempt was made to classify the glass and glass-ceramics used in SOFC, and the sealing glasses for SOFC based on different systems (silicate sealing, borosilicate sealing, aluminosilicate sealing and boroalumino-silicate sealing) were introduced. The development trend of glass and glass-ceramics in SOFC was prospected.
- solid oxide fuel cell （SOFC） /
- glass /
- glass-ceramics /
- sealing /
- thermochemical stability

HTML全文

图 1 典型的平板型SOFC密封结构^[8]

Figure 1. Typical sealing configurations in planar SOFC

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图 2 BABS密封剂与Crofer22APU在800 ℃下保温30 h后的橫截面的SEM^[30]

Figure 2. Back scattered electron micrographs of cross-section interfaces between glass-ceramic sealants and SDC electrolyte after crystallization at 800 ℃ for 30 h

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图 3 不同气氛下玻璃网络结构的示意图^[33]

Figure 3. Schematic network structure of glasses

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图 4 在800 ℃下密封并在600 ℃下保温100 h后，BCABS玻璃与电解质界面的横截面SEM图像^[34]

Figure 4. Cross-sectional SEM images of interface between BCABS glass and electrolyte after sealing at 800 ℃ and keeping warm at 600 ℃ for 100 h

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