Citation: | TANG Wen, LI Yue, GUO Yingjun, LYU Yuejing. Study on fusion diffusion characteristics of bio-based rejuvenator-asphalt at micro scale[J]. Journal of Shanghai University of Engineering Science, 2022, 36(1): 46-54. doi: 10.12299/jsues.21-0190 |
The molecular dynamics method was used to construct the bio-based rejuvenator-asphalt model, and the fusion diffusion behavior of bio-based rejuvenator-asphalt was investigated by microscopic simulation. Firstly, the FTIR test combined with the SARA model was used to determine the molecular structure of 12 kinds of asphalt before and after aging. And the main components of animal waste bio-based rejuvenators including steroids and carboxylic acids were selected to establish the molecular dynamics model of the asphalt-rejuvenator diffusion system. Furthermore, the density and compatibility index were used to verify the reliability of the molecular dynamics model, and the fusion diffusion behavior of bio-based rejuvenator in virgin asphalt and aged asphalt were analyzed under different temperatures and aging conditions . The results show that the diffusion coefficients of bio-based rejuvenator in aged asphalt is higher than that in virgin asphalt. The diffusion performance of steroids is better than carboxylic acids at the same temperature. The diffusion coefficients of two bio-based rejuvenators increase with the increase of temperature, since the greater kinetic energy at high temperature makes it easier for the system molecules to get rid of the constraint of molecular force.
[1] |
张文,龙军,任强, 等. 沥青质分子聚集行为研究进展[J] . 化工进展,2019,38(5):2158 − 2163.
|
[2] |
ZAUMANIS M, MALLICK R B, POULIKAKOS L, et al. Influence of six rejuvenators on the performance properties of Reclaimed Asphalt Pavement (RAP) binder and 100% recycled asphalt mixtures[J] . Construction and Building Materials,2014,71:538 − 550. doi: 10.1016/j.conbuildmat.2014.08.073
|
[3] |
徐刚, 杨军, 朱浩然, 等. 生物再生剂再生效率研究[J] . 石油沥青,2017,31(1):14 − 20. doi: 10.3969/j.issn.1006-7450.2017.01.003
|
[4] |
高新文, 刘朝晖. 生物油再生沥青自愈合机理分析[J] . 中国公路学报,2019,32(4):235 − 242.
|
[5] |
季节, 李鹏飞, 杨松, 等. 生物型沥青再生剂对老化沥青再生性能的影响[J] . 石油沥青,2015,29(4):1 − 6. doi: 10.3969/j.issn.1006-7450.2015.04.001
|
[6] |
BOWERS B F, HUANG B S, SHU X, et al. Investigation of reclaimed asphalt pavement blending efficiency through GPC and FTIR[J] . Construction and building materials,2014,50:517 − 523. doi: 10.1016/j.conbuildmat.2013.10.003
|
[7] |
MOHAJERI M, MOLENAAR A A A, VAN DE VEN M F C. Experimental study into the fundamental understanding of blending between reclaimed asphalt binder and virgin bitumen using nanoindentation and nano-computed tomography[J] . Road Materials and Pavement Design,2014,15(2):372 − 384. doi: 10.1080/14680629.2014.883322
|
[8] |
MA T, HUANG X M, ZHAO Y L, et al. Evaluation of the diffusion and distribution of the rejuvenator for hot asphalt recycling[J] . Construction and Building Materials,2015,98:530 − 536. doi: 10.1016/j.conbuildmat.2015.08.135
|
[9] |
CONG P L, HAO H J, ZHANG Y H, et al. Investigation of diffusion of rejuvenator in aged asphalt[J] . International Journal of Pavement Research and Technology,2016,9(4):280 − 288. doi: 10.1016/j.ijprt.2016.08.001
|
[10] |
XU G J, WANG H, SUN W. Molecular dynamics study of rejuvenator effect on RAP binder: Diffusion behavior and molecular structure[J] . Construction and Building Materials,2018,158:1046 − 1054. doi: 10.1016/j.conbuildmat.2017.09.192
|
[11] |
ZADSHIR M, HOSSEINNEZHAD S, FINI E H. Deagglomeration of oxidized asphaltenes as a measure of true rejuvenation for severely aged asphalt binder[J] . Construction and Building Materials,2019,209:416 − 424. doi: 10.1016/j.conbuildmat.2019.03.090
|
[12] |
MENG F, MA S, MUHAMMAD Y, et al. Analysis of virgin asphalt brands via the integrated application of FTIR and gel permeation chromatography[J] . Arabian Journal for Science and Engineering,2020,45(10):7999 − 8009. doi: 10.1007/s13369-020-04539-x
|
[13] |
HOU X D, LYU S T, CHEN Z, et al. Applications of fourier transform infrared spectroscopy technologies on asphalt materials[J] . Measurement,2018,121:304 − 316. doi: 10.1016/j.measurement.2018.03.001
|
[14] |
LI D D, GREENFIELD M L. Chemical compositions of improved model asphalt systems for molecular simulations[J] . Fuel,2014,115:347 − 356. doi: 10.1016/j.fuel.2013.07.012
|
[15] |
FINI E H, KALBERER E W, SHAHBAZI A. Biobinder from swine manure: Sustainable alternative for asphalt binder[C]// Proceedings of Transportation Research Board 90th Annual Meeting. Washington DC: Transportation Research Board, 2011.
|
[16] |
PAHLAVAN F, MOUSAVI M, HUNG A M, et al. Characterization of oxidized asphaltenes and the restorative effect of a bio-modifier[J] . Fuel,2018,212:593 − 604. doi: 10.1016/j.fuel.2017.10.090
|
[17] |
HUANG M, ZHANG H L, GAO Y, et al. Study of diffusion characteristics of asphalt-aggregate interface with molecular dynamics simulation[J] . International Journal of Pavement Engineering,2019,22(3):319 − 330. doi: 10.1080/10298436.2019.1608991
|
[18] |
WANG P, DONG Z J, TAN Y Q, et al. Investigating the interactions of the saturate, aromatic, resin, and asphaltene four fractions in asphalt binders by molecular simulations[J] . Energy & Fuels,2015,29(1):112 − 121.
|