| Citation: | XU Yue, ZENG Zheng, YUAN Haikuan, LU Jie. Preparation and characterization of SPTA−PVA/CDA−GO/PVDF composite membrane[J]. Journal of Shanghai University of Engineering Science, 2022, 36(4): 341-346. doi: 10.12299/jsues.22-0132
|
Graphene oxide (GO) was modified by 1,4−cyclohexanediamine (CDA), and polyvinyl alcohol (PVA) was crosslinked by 4−sulfophthalic acid (SPTA). Hydrophilized polyvinylidene fluoride (PVDF) ultrafiltration membrane as support, SPTA−PVA/CDA−GO/PVDF composite membrane was prepared through vacuum filtration and drop coating. The composite membrane was characterized by ATR−FTIR, SEM and contact angle, and the pervaporation desalination performance of composite membrane was tested. The results show that the modification of CDA extended the interlayer spacing of GO nanosheets, thus improving the water permeability of CDA−GO layer, and the crosslinked PVA layer enhanced the surface hydrophilicity and stability of composite membrane, consequently, improved the water absorption and water transport properties of composite membrane. The composite membrane obtained a flux of 15.6 kg/(m2•h) and a rejection of 99.99% when treating with concentration of 3.5% NaCl solution at 70 ℃.
| [1] |
SHANNON M A, BOHN P W, ELIMELECH M, et al. Science and technology for water purification in the coming decades[J] . Nature,2008,452:301 − 310. doi: 10.1038/nature06599
|
| [2] |
ELIMELECH M, PHILLIP W A. The future of seawater desalination: Energy, technology, and the environment[J] . Science,2011,333:712 − 717. doi: 10.1126/science.1200488
|
| [3] |
王华, 刘艳飞, 彭东明, 等. 膜分离技术的研究进展及应用展望[J] . 应用化工,2013,42(3):532 − 534.
|
| [4] |
SALEEM H, ZAIDI S J. Nanoparticles in reverse osmosis membranes for desalination: A state of the art review[J] . Desalination,2020,475:114171. doi: 10.1016/j.desal.2019.114171
|
| [5] |
ZHAO P B, MENG J Q, ZHANG R, et al. Molecular design of chlorine-resistant polymer for pervaporation desalination[J] . Separation and Purification Technology,2021,268:11867.
|
| [6] |
CHEN X, ZHU Y B, LIU J Z, et al. Ultrafast water evaporation through graphene membranes with subnanometer pores for desalination[J] . Journal of Membrane Science,2021,621:118934. doi: 10.1016/j.memsci.2020.118934
|
| [7] |
BOLTO B, TRAN T, HOANG M, et al. Crosslinked poly (vinyl alcohol) membranes[J] . Progress in Polymer Science,2009,34:969 − 981. doi: 10.1016/j.progpolymsci.2009.05.003
|
| [8] |
LIANG B, LI Q, CAO B, et al. Water permeance, permeability and desalination properties of the sulfonic acid functionalized composite pervaporation membranes[J] . Desalination,2018,433:132 − 140. doi: 10.1016/j.desal.2018.01.028
|
| [9] |
ALKHOUZAAM A, QIBLAWEY H. Functional GO-based membranes for water treatment and desalination: Fabrication methods, performance and advantages. A review[J] . Chemosphere,2021,274:129853. doi: 10.1016/j.chemosphere.2021.129853
|
| [10] |
LIANG B, ZHAN W, QI G G, et al. High performance graphene oxide/polyacrylonitrile composite pervaporation membranes for desalination applications[J] . Journal of Materials Chemistry A,2015,3(9):5140 − 5147. doi: 10.1039/C4TA06573E
|
| [11] |
LIN H, DANGWAL S, LIU R C, et al. Reduced wrinkling in GO membrane by grafting basal-plane groups for improved gas and liquid separations[J] . Journal of Membrane Science,2018,563:336 − 344. doi: 10.1016/j.memsci.2018.05.073
|
| [12] |
QIAN Y L, ZHOU C, HUANG A S. Cross-linking modification with diamine monomers to enhance desalination performance of graphene oxide membranes[J] . Carbon,2018,136:28 − 37. doi: 10.1016/j.carbon.2018.04.062
|
| [13] |
NIKKHAH S, TAHERMANSOURI H, CHEKIN F. Synthesis, characterization, and electrochemical properties of the modified graphene oxide with 4, 40-methylenedianiline[J] . Materials Letters,2018,211:323 − 327.
|
| [14] |
NIGIZ F U. Graphene oxide-sodium alginate membrane for seawater desalination through pervaporation[J] . Desalination,2020,485:114465.
|
| [15] |
ZHAO X Y, TONG Z Q, LIU X F, et al. Facile Preparation of polyamide−graphene oxide composite membranes for upgrading pervaporation desalination performances of hypersaline solutions[J] . Industrial & Engineering Chemistry Research,2020,59(26):12232 − 12238.
|
| [16] |
WANG Q Z, LI N, BOLTO B, et al. Desalination by pervaporation: A review[J] . Desalination,2016,387:46 − 60. doi: 10.1016/j.desal.2016.02.036
|
| [1] | ZHANG Jingwen, GE Zhangyi, WAN Zhaomei, LI Jiuxiao, MA Xiaopei, ZHANG Rui, WANG Renjie, ZHENG Yan, TAO Junzhou. Friction and wear properties of graphene reinforced titanium matrix composites[J]. Journal of Shanghai University of Engineering Science, 2024, 38(4): 395-399. doi: 10.12299/jsues.23-0272 |
| [2] | DAI Yuegang, WANG Yiqi, ZHANG Xiong, ZHAI Guangjun, WANG Jinguo. Study on Catalytic Performance of Cerium Oxide Nanocrystals with Exposed High-Energy Facet for Soot Particles[J]. Journal of Shanghai University of Engineering Science, 2018, 32(1): 1-7. doi: 10.3969/j.issn.1009-444X.2018.01.001 |
| [3] | LIN Liyun. Flame-Retardant Cotton Fabric Finished with Mg(OH)2 via In-Situ Preparation[J]. Journal of Shanghai University of Engineering Science, 2017, 31(4): 342-346. doi: 10.3969/j.issn.1009-444X.2017.04.011 |
| [4] | ZHOU Yadong, ZHU Shijun, ZHU Liping, QIAN Yong, WANG Jun. Hydromechanics Analysis of Solar Mask System Based on Hollow Infiltration Filter[J]. Journal of Shanghai University of Engineering Science, 2017, 31(3): 198-203. doi: 10.3969/j.issn.1009-444X.2017.03.002 |
| [5] | Catalytic Performance of Indium Supported Oxide Catalysts for Methanol Steam Reforming[J]. Journal of Shanghai University of Engineering Science, 2016, 30(1): 70-75. doi: 10.3969/j.issn.1009-444X.2016.01.015 |
| [6] | ZHAO Chenchen, XU Yilin, YIN Xueping, XU Jie, Tong Quan, BI Zilun, LIU Xijian. Synthesis and Photocatalytic Performance of Iron-Doped Titania[J]. Journal of Shanghai University of Engineering Science, 2015, 29(3): 262-265. doi: 10.3969/j.issn.1009-444X.2015.03.016 |
| [7] | OUYANG Guoxun, WEN Miaoqin, YANG Chen, PAN Qingfa, DING Ying. Preparation of Starch Adhesive by Oxidized Modification[J]. Journal of Shanghai University of Engineering Science, 2015, 29(2): 189-192. doi: 10.3969/j.issn.1009-444X.2015.02.020 |
| [8] | DING Jindian, LI Weizhen, JIANG Tianqi, XIA Zonglian, GAN Wenjun. Synthesis and Characterization of Amphiphilic Diblock Copolymer (Poly Styrene-Block-Poly Caprolactone)[J]. Journal of Shanghai University of Engineering Science, 2014, 28(2): 97-101. doi: 10.3969/j.issn.1009-444X.2014.02.001 |
| [9] | SUN Yan-hong, ZHAO Jia-chang, TANG Bo-he-jin, TANG Ao-min, LIAO Chen-min, XU Jing-li. Research Progress of Graphene-based Composite Materials[J]. Journal of Shanghai University of Engineering Science, 2011, 25(3): 252-257. doi: 10.3969/j.issn.1009-444X.2011.03.015 |
| [10] | LIU Lei, YU Zhi-shui, CHEN Jie. Research Status of Oxide Activity's Impact on Shape of Weld Pool[J]. Journal of Shanghai University of Engineering Science, 2010, 24(1): 89-94. doi: 10.3969/j.issn.1009-444X.2010.01.020 |
| [11] | ZHENG Jian-guo, XU Gang-bing, GAN Xin-yan, CHEN Feng-qin. Simulation and Analysis of Butadiene Extractive Distillation Process Based on DMF Method[J]. Journal of Shanghai University of Engineering Science, 2010, 24(3): 267-271. doi: 10.3969/j.issn.1009-444X.2010.03.019 |
| [12] | ZHAO Linjing, SONG Xiaoping, LI Fangya. Research Progress on Anti-oxidation of Polysaccharide and Its Derivatives[J]. Journal of Shanghai University of Engineering Science, 2008, 22(1): 44-47. doi: 10.3969/j.issn.1009-444X.2008.01.011 |
| [13] | HE Jia, LI Fang. Progress in Preparation of Nanocrystalline Alumina Ceramics[J]. Journal of Shanghai University of Engineering Science, 2008, 22(3): 211-214. doi: 10.3969/j.issn.1009-444X.2008.03.005 |
| [14] | TANG Bo-he-jin, WANG Ai-fen, JIANG Zheng-ye, LI Shou-hong, JIANG Zi-han, ZHANG Jia-le. Preparation and Properties of Alumina Catalyst Containing Silicon[J]. Journal of Shanghai University of Engineering Science, 2007, 21(4): 326-330. doi: 10.3969/j.issn.1009-444X.2007.04.010 |
| [15] | SUN Xiaoling, HAN Wenjun. New Progress in Catalytic Epoxidation Research of Terpenes[J]. Journal of Shanghai University of Engineering Science, 2007, 21(1): 25-29. doi: 10.3969/j.issn.1009-444X.2007.01.006 |
| [16] | LIU Xi-jian, LIU Ze-hua, XIAO Wen-fa, ZHANG Xin. Determination and Antioxidation Activities of Total Flavonoids of Hippophae[J]. Journal of Shanghai University of Engineering Science, 2006, 20(2): 135-139. doi: 10.3969/j.issn.1009-444X.2006.02.010 |
| [17] | CHEN Yan-qing, DING De-run, SHAG Ye, GU Li-peng. Preparation of Dy( Ⅲ ) - Low Molecular Chitosan Complex and its Antioxidant Activity[J]. Journal of Shanghai University of Engineering Science, 2005, 19(4): 306-308,313. doi: 10.3969/j.issn.1009-444X.2005.04.005 |
| [18] | Situation and Countermeasures of Pollution Controlling for Sulphur Dioxide Discharged from Industrial Coal-fired Boilers[J]. Journal of Shanghai University of Engineering Science, 2004, 18(2): 144-147. doi: 10.3969/j.issn.1009-444X.2004.02.012 |
| [19] | Study on Bleach Process of Ethoxylated Lauryl Alcohol Sulfates[J]. Journal of Shanghai University of Engineering Science, 2003, 17(1): 22-26. doi: 10.3969/j.issn.1009-444X.2003.01.005 |
| [20] | Mechanism and Practice of Reducing Nano Zinc Oxide Amount in Rubber[J]. Journal of Shanghai University of Engineering Science, 2002, 16(2): 96-98,104. doi: 10.3969/j.issn.1009-444X.2002.02.004 |
Copyright © Journal of Shanghai University of Engineering Science沪ICP备05052046号
Tel：86-21-67791000 Email：xuebao@sues.edu.cn
Address：333 Longteng Road, Shanghai, China China Pos：201620
Supported by:
Beijing Renhe Information Technology Co. Ltd
XU Yue, ZENG Zheng, YUAN Haikuan, LU Jie. Preparation and characterization of SPTA−PVA/CDA−GO/PVDF composite membrane[J]. Journal of Shanghai University of Engineering Science, 2022, 36(4): 341-346. doi: 10.12299/jsues.22-0132
DownLoad:
