玻璃和微晶玻璃在固体氧化物燃料电池中的研究进展

王坤; 苏钰

玻璃和微晶玻璃在固体氧化物燃料电池中的研究进展

王坤,
苏钰^,

上海工程技术大学材料工程学院, 上海 201620

基金项目: 上海工程技术大学研究生科研创新资助项目（20KY0503）；上海工程技术大学课程建设资助项目（01040610）

详细信息

作者简介:
王坤：王　坤（1995−），男，在读硕士，研究方向为固体氧化物燃料电池. E-mail: 1901962908@qq.com

通讯作者:
苏　钰（1977−），女，副教授，博士，研究方向为高强钢成形性. E-mail: suyu@sues.edu.cn

中图分类号: TM911.4
计量
- 文章访问数: 708
- HTML全文浏览量: 336
- PDF下载量: 377
- 被引次数: 0
出版历程
- 收稿日期: 2021-06-03
- 刊出日期: 2021-09-30

Application of glass and glass-ceramics in solid oxide fuel cell

WANG Kun,
SU Yu^,

School of Materials Engineering, Shanghai University of Engineering Science, Shanghai 201620, China

摘要

摘要: 描述玻璃和微晶玻璃作为固体氧化物燃料电池(Solid Oxide Fuel Cell，SOFC)密封材料的使用要求. 尝试基于SOFC所用的玻璃和微晶玻璃进行分类，介绍基于不同体系的SOFC用密封玻璃(硅酸盐密封、硼硅酸密封、铝硅酸盐密封和硼铝硅酸盐密封)，并对玻璃和微晶玻璃在SOFC中的发展趋势进行展望.
- 固体氧化物燃料电池 /
- 玻璃 /
- 微晶玻璃 /
- 密封 /
- 热化学稳定性
Abstract: The application requirements of glass and glass-ceramics as solid oxide fuel cell (SOFC) sealing materials were described. An attempt was made to classify the glass and glass-ceramics used in SOFC, and the sealing glasses for SOFC based on different systems (silicate sealing, borosilicate sealing, aluminosilicate sealing and boroalumino-silicate sealing) were introduced. The development trend of glass and glass-ceramics in SOFC was prospected.
- solid oxide fuel cell （SOFC） /
- glass /
- glass-ceramics /
- sealing /
- thermochemical stability

HTML全文

图 1 典型的平板型SOFC密封结构^[8]

Figure 1. Typical sealing configurations in planar SOFC

下载: 全尺寸图片幻灯片

图 2 BABS密封剂与Crofer22APU在800 ℃下保温30 h后的橫截面的SEM^[30]

Figure 2. Back scattered electron micrographs of cross-section interfaces between glass-ceramic sealants and SDC electrolyte after crystallization at 800 ℃ for 30 h

下载: 全尺寸图片幻灯片

图 3 不同气氛下玻璃网络结构的示意图^[33]

Figure 3. Schematic network structure of glasses

下载: 全尺寸图片幻灯片

图 4 在800 ℃下密封并在600 ℃下保温100 h后，BCABS玻璃与电解质界面的横截面SEM图像^[34]

Figure 4. Cross-sectional SEM images of interface between BCABS glass and electrolyte after sealing at 800 ℃ and keeping warm at 600 ℃ for 100 h

下载: 全尺寸图片幻灯片

参考文献(36)

[1]	MANDEEP S, DARIO Z, ELISABETTA C. Solid oxide fuel cell: Decade of progress, future perspectives and challenges[J] . International Journal of Hydrogen Energy,2021,46(54):27643 − 27674.
[2]	HADI N H, SOMALU M R, SAMAT A A, et al. A review on the preparation of anode materials and anode films for solid oxide fuel cell applications[J] . International Journal of Energy Research,2021,45(10):14357 − 14388. doi: 10.1002/er.6763
[3]	ZHANG X B, JIN Y M, LI D, et al. A review on recent advances in micro-tubular solid oxide fuel cells[J] . Journal of Power Sources,2021,506:230135.
[4]	YU F Y, HAN T T, WANG Z G, et al. Recent progress in direct carbon solid oxide fuel cell: Advanced anode catalysts, diversified carbon fuels, and heat management[J] . International Journal of Hydrogen Energy,2021,46(5):4283 − 4300. doi: 10.1016/j.ijhydene.2020.10.259
[5]	SU H R, HU Y H. Progress in low-temperature solid oxide fuel cells with hydrocarbon fuels[J] . Chemical Engineering Journal,2020,402:126235. doi: 10.1016/j.cej.2020.126235
[6]	JULIA S, GRAEME W W. Computational modelling of solid oxide fuel cells[J] . Current Opinion in Electrochemistry,2020,21:14 − 21. doi: 10.1016/j.coelec.2019.12.007
[7]	MAHMUD L S, MUCHTAR A, SOMALUA M R. Challenges in fabricating planar solid oxide fuel cells: A review[J] . Renewable and Sustainable Energy,2017,72:105 − 116. doi: 10.1016/j.rser.2017.01.019
[8]	DILSHAT U, TULYAGANOV, ALLU A R, et al. Aluminosilicate-based sealants for SOFCs and other electrochemical applications: A brief review[J] . Journal of Power Sources,2013,242:486 − 502. doi: 10.1016/j.jpowsour.2013.05.099
[9]	WANG S F, LU H C, LIU Y X, et al. Characteristics of glass sealants forintermediate-temperature solid oxide fuel cell applications[J] . Ceramics International,2017,43(1):S613 − S620.
[10]	YUTO W, YUYA T, HIRONORI N, et al. Visualization and mechanical strength of glass seal in planar type solid oxide fuel cells[J] . International Journal of Hydrogen Energy,2020,45(41):21754 − 21766. doi: 10.1016/j.ijhydene.2020.05.153
[11]	LUO L H, LIN Y C, HUANG Z Z, et al. Application of BaO-CaO-Al₂O₃-B₂O₃-SiO₂ glass-ceramic seals in large size planar IT-SOFC[J] . Ceramics International,2015,41(8):9239 − 9243. doi: 10.1016/j.ceramint.2015.01.091
[12]	MAHAPATRA M K, LU K. Glass-based seals for solid oxide fuel and electrolyzer cells: A review[J] . Materials Science and Engineering R,2009,67(5-6):65 − 85.
[13]	HEYDARI F, MAGHSOUDIPOUR A, HAMNABARD Z, et al. Evaluation on properties of CaO-BaO-B₂O₃-Al₂O₃-SiO₂ glassceramic sealants for intermediate temperature solid oxide fuel cells[J] . Journal of Materials Science and Technology,2013,29(1):49 − 54. doi: 10.1016/j.jmst.2012.11.011
[14]	GARAI M, SINGH S P, KARMAKAR B. Mica (KMg₃AlSi₃O₁₀F₂) based glass-ceramic composite sealant with thermal stability for SOFC application[J] . International Journal of Hydrogen Energy,2021,46(45):23480 − 23488. doi: 10.1016/j.ijhydene.2020.10.252
[15]	YEONG-SHYUNG C, STEVENSON J W. Long-term thermal cycling of Phlogopite mica-based compressive seals for solid oxide fuel cells[J] . Journal of Power Sources,2005,140(2):340 − 345. doi: 10.1016/j.jpowsour.2004.08.030
[16]	WANG X C, ZHANG W, LI R Z, et al. Development of a novel compressive h-BN based seal for planar intermediate temperature SOFC[J] . Ceramics International,2018,44(6):6272 − 6277. doi: 10.1016/j.ceramint.2018.01.015
[17]	SUN Z, ZHANG L X, LI X, et al. Reactive air brazing of the YSZ/AISI 310s couples using a novel Ag-Nb₂O₅ sealant[J] . Ceramics International,2020,46(4):5168 − 5174. doi: 10.1016/j.ceramint.2019.10.262
[18]	WANG Z Q, LI C, SI X Q, et al. Brazing YSZ ceramics by a novel SiO₂ nanoparticles modified Ag filler[J] . Ceramics International,2020,46(10):16493 − 16501. doi: 10.1016/j.ceramint.2020.03.214
[19]	BORHAN A I, GROMADA M, NEDELCU G G, et al. Influence of (CoO, CaO, B₂O₃) additives on thermal and dielectric properties of BaO-Al₂O₃-SiO₂ glass-ceramic sealant for OTM applications[J] . Ceramics International,2016,42(8):10459 − 10468. doi: 10.1016/j.ceramint.2016.03.199
[20]	ELSAYED H, JAVED H, SABATO A G, et al. Novel glass-ceramic SOFC sealants from glass powders and a reactive silicone binder[J] . Journal of the European Ceramic Society,2018,38(12):4245 − 4251. doi: 10.1016/j.jeurceramsoc.2018.05.024
[21]	LUO Z, LEI W, LIANG H, et al. Improving sealing properties of CaO-SrO-Al₂O₃-SiO₂ glass and glass-ceramics for solid oxide fuel cells: Effect of La₂O₃ addition[J] . Ceramics International,2020,46(11):17698 − 17706. doi: 10.1016/j.ceramint.2020.04.074
[22]	YEONG S C, STEVENSON J W, SINGH P. Thermal cycle stability of a novel glass-mica composite seal for solid oxide fuel cells: Effect of glass volume fraction and stresses[J] . Journal of Power Sources,2005,152:168 − 174. doi: 10.1016/j.jpowsour.2005.03.213
[23]	GARAI M, KARMAKAR B. Zr⁺⁴-controlled nucleation and microstructure in Si-Mg-Al-K-B-F glass-ceramic sealant (solid oxide fuel cell)[J] . Materialstoday Energy,2020,18:100535.
[24]	LI R Z, LIANG X P, WANG X C, et al. Improvement of sealing performance for Al₂O₃ fiber-reinforced compressive seals for intermediate temperature solid oxide fuel cell[J] . Ceramics International,2019,45(17):21953 − 21959. doi: 10.1016/j.ceramint.2019.07.209
[25]	WU Z, HU R, ZHANG T B, et al. Moisture induced environmental embrittlement of a high Nb containing TiAl alloy[J] . Materials Science and Engineering:A,2017,701:214 − 220. doi: 10.1016/j.msea.2017.06.064
[26]	PASCUAL M J, GUILLET A, DURÁN A. Optimization of glass-ceramic sealant compositions in the system MgO–BaO–SiO₂ for solid oxide fuel cells (SOFC)[J] . Journal of Power Sources,2007,169(1):40 − 46. doi: 10.1016/j.jpowsour.2007.01.040
[27]	CHRISTIAN T, CHRISTIAN R. High thermal expansion of crystallized glasses in the system BaO-ZnO-NiO-SiO₂[J] . Ceramics International,2015,41(10):13310 − 13319. doi: 10.1016/j.ceramint.2015.07.114
[28]	RODRÍGUEZ-LÓPEZ S, HAANAPPEL V A C, DURÁN A, et al. Glass-ceramic seals in the system MgO-BaO-B₂O₃-SiO₂ operating under simulated SOFC conditions[J] . International Journal of Hydrogen Energy,2016,41(34):15335 − 15345. doi: 10.1016/j.ijhydene.2016.07.051
[29]	SILVA L D, RODRIGUES A M, RODRIGUES A C M, et al. Sintering and crystallization of SrO-CaO-B₂O₃-SiO₂ glass-ceramics with different TiO₂ contents[J] . Journal of Non-Crystalline Solids,2017,473:33 − 40. doi: 10.1016/j.jnoncrysol.2017.07.021
[30]	AYAWANNA J, KINGNOIA N, LAORODPHAN N. Effect of bismuth oxide on crystallization and sealing behavior of barium borosilicate glass sealant for SOFCs[J] . Journal of Non-Crystalline Solids,2019,509:48 − 53. doi: 10.1016/j.jnoncrysol.2019.01.028
[31]	SASWATI G A, SHARMA D, KUNDU P, et al. Development and characterizations of BaO-CaO-Al₂O₃-SiO₂ glass-ceramic sealants for intermediate temperature solid oxide fuel cell application[J] . Journal of Non-Crystalline Solids,2008,354(34):4081 − 4088. doi: 10.1016/j.jnoncrysol.2008.05.036
[32]	KRAINOVA D A, SAETOVAA N S, KUZMINA A V, et al. Non-crystallising glass sealants for SOFC: Effect of Y₂O₃ addition[J] . Ceramics International,2020,46(4):5193 − 5200. doi: 10.1016/j.ceramint.2019.10.266
[33]	WANG X L, OU D R, ZHAO Z, et al. Stability of SrO-La₂O₃-Al₂O₃-SiO₂ glass sealants in high-temperature air and steam[J] . Ceramics International,2016,42(6):7514 − 7523. doi: 10.1016/j.ceramint.2016.01.158
[34]	LIU L G, LUO L H, QIN Y, et al. Study on non-isothermal crystallization kinetics of the BaO-CaO-Al₂O₃-B₂O₃-SiO₂ glass for IT-SOFCs sealing[J] . Ceramics International,2018,44(17):21277 − 21283. doi: 10.1016/j.ceramint.2018.08.176
[35]	KUMAR V, KAUR G, LU K, et al. Interfacial compatibility of alumino-borosilicate glass sealants with AISI 441 and YSZ for different atmospheres[J] . International Journal of Hydrogen Energy,2015,40(2):1195 − 1202. doi: 10.1016/j.ijhydene.2014.11.037
[36]	REN M Y, YANG P, XU J, et al. Effect of nickel doping on structure and suppressing boron volatility of borosilicate glass sealants in solid oxide fuel cells[J] . Journal of the European Ceramic Society,2019,39(6):2179 − 2185. doi: 10.1016/j.jeurceramsoc.2019.01.034