甲烷干重整制氢催化剂抗积碳性能研究进展

闫金彪; 王莎; 张华荣

doi:10.12299/jsues.22-0093

甲烷干重整制氢催化剂抗积碳性能研究进展

doi: 10.12299/jsues.22-0093

上海工程技术大学机械与汽车工程学院，上海 201620

基金项目: 国家自然科学基金项目资助（51704194）；上海市扬帆科技人才计划资助（19YF1418000）；上海工程技术大学青年科研团队培育计划项目资助（QNTD202101）

详细信息

作者简介:
闫金彪（1997−），男，在读硕士，研究方向为含碳能源高效高值利用. E-mail：yanjbiao_90@163.com

通讯作者:
王　莎（1984−），女，副教授，博士，研究方向为洁净能源联合循环发电热力系统优化、含碳能源热化学转换理论及低碳化利用. E-mail：wangsha@sues.edu.cn

中图分类号: TK91
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- 文章访问数: 667
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出版历程
- 收稿日期: 2022-04-21
- 刊出日期: 2023-03-31

Research progress of carbon deposition resistance of catalyst for dry reforming of methane to hydrogen

School of Mechanical and Automotive Engineering, Shanghai University of Engineering Science, Shanghai 201620, China

摘要

摘要: 现代工业制氢技术中，甲烷重整制氢具有反应物丰富、可利用性高等独特优势，尤其甲烷干重整（Dry Reforming of Methane, DRM）技术，以甲烷和二氧化碳为原料，兼具环境和经济效益，而催化剂积碳是影响DRM技术发展的主要问题之一. 从催化剂活性组分、载体和助剂方面，详细阐述催化剂组分相互作用、活性金属粒径、碱度、储氧能力和积碳类型对DRM催化剂抗积碳性能的影响. 分析发现活性金属和载体的强相互作用、双金属的协同作用以及较小的活性金属颗粒均有助于减少积碳和提高催化剂活性，提高催化剂的储氧能力能促进碳脱除，积碳类型及数量与载体密切相关，载体碱度适中有助于增强CO₂的活化，提高催化剂抗积碳能力. 研究结果为甲烷干重整制氢催化剂的设计和优化提供参考.
- 制氢 /
- 催化剂 /
- 抗积碳性能 /
- 甲烷干重整
Abstract: Among modern industrial hydrogen production technologies, methane reforming for hydrogen production has unique advantages in rich reactant sources and high availability, especially dry reforming of methane (DRM) technology, which uses methane and carbon dioxide as raw materials and has both environmental and economic benefits. Carbon deposition on catalyst is one of the main problems affecting the development of DRM technology. To design high-performance catalysts, current research mainly focuses on the active components, supports, and promoters. This article discusses in detail the effects of interaction between active components and supports, active metal particle size, basicity, oxygen storage capacity, and carbon deposition type on the carbon deposition resistance of DRM catalysts. The results indicate that strong interactions between active metals and supports, synergistic effects of bimetallic catalysts, and smaller active metal particles can reduce carbon deposition and improve catalyst activity. Increasing oxygen storage capacity can promote carbon removal. The type and amount of carbon deposition are closely related to the support material, and moderate support basicity can promote CO₂ activation, thereby improving the carbon deposition resistance of the catalyst. This article provides a reference for the design and optimization of DRM catalysts.
- hydrogen production /
- catalyst /
- carbon deposition resistance /
- dry reforming of methane (DRM)

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参考文献(38)

[1]	曹军文, 张文强, 李一枫, 等. 中国制氢技术的发展现状[J] . 化学进展,2021,33(12):2215 − 2244.
[2]	刘勇, 李江华, 李思梦, 等. CH₄/CO₂等离子体重整反应的研究进展[J] . 天然气化工,2017,42(5):120 − 125.
[3]	TURAP Y S, WANG I W, FU T T, et al. Co–Ni alloy supported on CeO₂ as a bimetallic catalyst for dry reforming of methane[J] . International Journal of Hydrogen Energy,2020,45(11):6538 − 6548. doi: 10.1016/j.ijhydene.2019.12.223
[4]	LE SACHÉ E, PASTOR-PÉREZ L, WATSON D, et al. Ni stabilised on inorganic complex structures: Superior catalysts for chemical CO₂ recycling via dry reforming of methane[J] . Applied Catalysis B: Environmental,2018,236:458 − 465. doi: 10.1016/j.apcatb.2018.05.051
[5]	KUMAR R, KUMAR K, PANT K K, et al. Tuning the metal-support interaction of methane tri-reforming catalysts for industrial flue gas utilization[J] . International Journal of Hydrogen Energy,2020,45(3):1911 − 1929. doi: 10.1016/j.ijhydene.2019.11.111
[6]	RUCKENSTEIN E, WANG H Y. Carbon dioxide reforming of methane to synthesis gas over supported cobalt catalysts[J] . Applied Catalysis A: General,2000,204(2):257 − 263. doi: 10.1016/S0926-860X(00)00674-8
[7]	BU K K, KUBOON S C, DENG J, et al. Methane dry reforming over boron nitride interface-confined and LDHs-derived Ni catalysts[J] . Applied Catalysis B: Environmental,2019,252:86 − 97. doi: 10.1016/j.apcatb.2019.04.007
[8]	JANG W J, JEONG D W, SHIM J O, et al. Metal oxide (MgO, CaO, and La₂O₃) promoted Ni-Ce_0.8Zr_0.2O₂ catalysts for H₂ and CO production from two major greenhouse gases[J] . Renewable Energy,2015,79:91 − 95. doi: 10.1016/j.renene.2014.08.032
[9]	ARAMOUNI N A K, TOUMA J G, TARBOUSH B A, et al. Catalyst design for dry reforming of methane: Analysis review[J] . Renewable and Sustainable Energy Reviews,2018,82:2570 − 2585. doi: 10.1016/j.rser.2017.09.076
[10]	ZHANG L J, WANG F G, ZHU J Y, et al. CO₂ reforming with methane reaction over Ni@SiO₂ catalysts coupled by size effect and metal-support interaction[J] . Fuel,2019,256:115954. doi: 10.1016/j.fuel.2019.115954
[11]	DAS S, P´EREZ-RAMÍREZ J, GONG J L, et al. Core-shell structured catalysts for thermocatalytic, photocatalytic, and electrocatalytic conversion of CO₂[J] . Chemical Society Reviews,2020,49(10):2937 − 3004. doi: 10.1039/C9CS00713J
[12]	KIM W Y, JANG J S, RA E C, et al. Reduced perovskite LaNiO₃ catalysts modified with Co and Mn for low coke formation in dry reforming of methane[J] . Applied Catalysis A: General,2019,575:198 − 203. doi: 10.1016/j.apcata.2019.02.029
[13]	ARAMOUNI N A K, ZEAITER J, KWAPINSKI W, et al. Eclectic trimetallic Ni–Co–Ru catalyst for the dry reforming of methane[J] . International Journal of Hydrogen Energy,2020,45(35):17153 − 17163. doi: 10.1016/j.ijhydene.2020.04.261
[14]	WU H J, PANTALEO G, PAROLA V L, et al. Bi-and trimetallic Ni catalysts over Al₂O₃ and Al₂O₃−MO_x (M= Ce or Mg) oxides for methane dry reforming: Au and Pt additive effects[J] . Applied Catalysis B: Environmental,2014,156:350 − 361.
[15]	KAWI S, KATHIRASER Y, NI J, et al. Progress in synthesis of highly active and stable nickel‐based catalysts for carbon dioxide reforming of methane[J] . ChemSusChem,2015,8(21):3556 − 3575. doi: 10.1002/cssc.201500390
[16]	SONG K, LU M, XU S, et al. Effect of alloy composition on catalytic performance and coke-resistance property of Ni−Cu/Mg(Al)O catalysts for dry reforming of methane[J] . Applied Catalysis B: Environmental,2018,239:324 − 333. doi: 10.1016/j.apcatb.2018.08.023
[17]	HORLYCK J, LAWREY C, LOVELL E C, et al. Elucidating the impact of Ni and Co loading on the selectivity of bimetallic NiCo catalysts for dry reforming of methane[J] . Chemical Engineering Journal,2018,352:572 − 580. doi: 10.1016/j.cej.2018.07.009
[18]	ZHANG J G, WANG H, DALAI A K. Development of stable bimetallic catalysts for carbon dioxide reforming of methane[J] . Journal of Catalysis,2007,249(2):300 − 310. doi: 10.1016/j.jcat.2007.05.004
[19]	THEOFANIDIS S A, GALVITA V V, POELMAN H, et al. Enhanced carbon-resistant dry reforming Fe-Ni catalyst: Role of Fe[J] . Acs Catalysis,2015,5(5):3028 − 3039. doi: 10.1021/acscatal.5b00357
[20]	GUHAROY U, SACHÉ E L, CAI Q, et al. Understanding the role of Ni-Sn interaction to design highly effective CO₂ conversion catalysts for dry reforming of methane[J] . Journal of CO₂ Utilization,2018,27:1 − 10. doi: 10.1016/j.jcou.2018.06.024
[21]	NÉMETH M, SÁFRÁN G, HORVÁTH A, et al. Hindered methane decomposition on a coke-resistant Ni-In/SiO₂ dry reforming catalyst[J] . Catalysis Communications,2019,118:56 − 59. doi: 10.1016/j.catcom.2018.10.003
[22]	XIE Z H, YAN B H, KATTEL S, et al. Dry reforming of methane over CeO₂-supported Pt-Co catalysts with enhanced activity[J] . Applied Catalysis B: Environmental,2018,236:280 − 293. doi: 10.1016/j.apcatb.2018.05.035
[23]	HAN J W, PARK J S, CHOI M S, et al. Uncoupling the size and support effects of Ni catalysts for dry reforming of methane[J] . Appl ied Catal ysis B: Environ mental,2017,203:625 − 632. doi: 10.1016/j.apcatb.2016.10.069
[24]	WANG J, ZHANG J, ZHONG H X, et al. Effect of support morphology and size of nickel metal ions on hydrogen production from methane steam reforming[J] . Chemical Physics Letters,2020,746:137291. doi: 10.1016/j.cplett.2020.137291
[25]	KANG D W, YU J, MA W H, et al. Synthesis of Cu/Ni-La_0.7Sr_0.3Cr_0.5Mn_0.5O_3-δ and its catalytic performance on dry methane reforming[J] . Journal of Rare Earths,2019,37:585 − 593. doi: 10.1016/j.jre.2018.10.016
[26]	TIAN J Q, LI H C, ZENG X, et al. Facile immobilization of Ni nanoparticles into mesoporous MCM-41 channels for efficient methane dry reforming[J] . Chinese Journal of Catalysis,2019,40:1395 − 1404. doi: 10.1016/S1872-2067(19)63403-0
[27]	BALLARINI A, BASILE F, BENITO P, et al. Platinum supported on alkaline and alkaline earth metal-doped alumina as catalysts for dry reforming and partial oxidation of methane[J] . Applied Catalysis A: General,2012,433:1 − 11.
[28]	SENGUPTA S, DEO G. Modifying alumina with CaO or MgO in supported Ni and Ni-Co catalysts and its effect on dry reforming of CH₄[J] . Journal of CO₂ Utilization,2015,10:67 − 77. doi: 10.1016/j.jcou.2015.04.003
[29]	DAMA S, GHODKE S R, BOBADE R, et al. Active and durable alkaline earth metal substituted perovskite catalysts for dry reforming of methane[J] . Applied Catalysis B: Environmental,2018,224:146 − 158. doi: 10.1016/j.apcatb.2017.10.048
[30]	ZHU J Q, PENG X X, YAO L, et al. Synthesis gas production from CO₂ reforming of methane over Ni-Ce/SiO₂ catalyst: The effect of calcination ambience[J] . International Journal of Hydrogen Energy,2013,38(1):117 − 126. doi: 10.1016/j.ijhydene.2012.07.136
[31]	WANG F G, XU L L, YANG J, et al. Enhanced catalytic performance of Ir catalysts supported on ceria-based solid solutions for methane dry reforming reaction[J] . Catalysis Today,2017,281:295 − 303. doi: 10.1016/j.cattod.2016.03.055
[32]	CHEIN R Y, FUNG W Y. Syngas production via dry reforming of methane over CeO₂ modified Ni/Al₂O₃ catalysts[J] . International Journal of Hydrogen Energy,2019,44(28):14303 − 14315. doi: 10.1016/j.ijhydene.2019.01.113
[33]	BIAN Z F, WANG Z G, JIANG B, et al. A review on perovskite catalysts for reforming of methane to hydrogen production[J] . Renewable and Sustainable Energy Reviews,2020,134:110291. doi: 10.1016/j.rser.2020.110291
[34]	PICHAS C, POMONIS P, PETRAKIS D, et al. Kinetic study of the catalytic dry reforming of CH₄ with CO₂ over La_2-xSr_xNiO₄ perovskite-type oxides[J] . Applied Catalysis A: General,2010,386(1-2):116 − 123. doi: 10.1016/j.apcata.2010.07.043
[35]	SUTTHIUMPORN K, KAWI S. Promotional effect of alkaline earth over Ni-La₂O₃ catalyst for CO₂ reforming of CH₄: Role of surface oxygen species on H₂ production and carbon suppression[J] . International Journal of Hydrogen Energy,2011,36(22):14435 − 14446. doi: 10.1016/j.ijhydene.2011.08.022
[36]	XU J K, ZHOU W, WANG J H, et al. Characterization and analysis of carbon deposited during the dry reforming of methane over Ni/La₂O₃/Al₂O₃ catalysts[J] . Chinese Journal of Catalysis,2009,30(11):1076 − 1084. doi: 10.1016/S1872-2067(08)60139-4
[37]	GUO J J, LOU H, ZHENG X M. The deposition of coke from methane on a Ni/MgAl₂O₄ catalyst[J] . Carbon,2007,45(6):1314 − 1321. doi: 10.1016/j.carbon.2007.01.011
[38]	YAO Z W, JIANG J, ZHAO Y, et al. Insights into the deactivation mechanism of metal carbide catalysts for dry reforming of methane via comparison of nickel-modified molybdenum and tungsten carbides[J] . RSC advances,2016,6(24):19944 − 19951. doi: 10.1039/C5RA24815A

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甲烷干重整制氢催化剂抗积碳性能研究进展

doi: 10.12299/jsues.22-0093

作者简介:
闫金彪（1997−），男，在读硕士，研究方向为含碳能源高效高值利用. E-mail：yanjbiao_90@163.com

通讯作者:
王　莎（1984−），女，副教授，博士，研究方向为洁净能源联合循环发电热力系统优化、含碳能源热化学转换理论及低碳化利用. E-mail：wangsha@sues.edu.cn

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Research progress of carbon deposition resistance of catalyst for dry reforming of methane to hydrogen

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留言板

甲烷干重整制氢催化剂抗积碳性能研究进展

doi: 10.12299/jsues.22-0093

作者简介: 闫金彪（1997−），男，在读硕士，研究方向为含碳能源高效高值利用. E-mail：yanjbiao_90@163.com

通讯作者: 王 莎（1984−），女，副教授，博士，研究方向为洁净能源联合循环发电热力系统优化、含碳能源热化学转换理论及低碳化利用. E-mail：wangsha@sues.edu.cn

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Research progress of carbon deposition resistance of catalyst for dry reforming of methane to hydrogen

计量

出版历程

目录

作者简介:
闫金彪（1997−），男，在读硕士，研究方向为含碳能源高效高值利用. E-mail：yanjbiao_90@163.com

通讯作者:
王　莎（1984−），女，副教授，博士，研究方向为洁净能源联合循环发电热力系统优化、含碳能源热化学转换理论及低碳化利用. E-mail：wangsha@sues.edu.cn